Kinetic View on a Catalyst for the Synthesis of But-2-yne-1,4-diol

Authors

  • J. Aubrecht Department of Organic Technology, University of Chemistry and Technology, Prague, Czech Republic
  • Q. Smejkal EnProCo-Berlin GmbH, Berlin, Germany
  • J. Januščák Department of Organic Technology, University of Chemistry and Technology, Prague, Czech Republic
  • P. Kukula Ranido s.r.o., Prague, Czech Republic
  • O. Matuška Department of Organic Technology, University of Chemistry and Technology, Prague, Czech Republic
  • P. Kačer Department of Organic Technology, University of Chemistry and Technology, Prague, Czech Republic

Keywords:

kinetic study, Reppe's reaction, 1,4-butynediol

Abstract

Reppe's reaction is one of a C≡C single bond forming reaction which is often used in the synthesis of but-2-yne-1,4-diol from formaldehyde and acetylene. Most of the producers of but-2-yne-1,4-diol use only one type of commercially available catalyst for Reppe's process. In this work, a simplified kinetic behaviour of the reaction using the prepared catalyst is described and the kinetic parameters (reaction constant, activation energy and pre-exponential factor) are evaluated.

Published

2017-01-15

How to Cite

Aubrecht, J., Smejkal, Q., Januščák, J., Kukula, P., Matuška, O., & Kačer, P. (2017). Kinetic View on a Catalyst for the Synthesis of But-2-yne-1,4-diol. Chemické Listy, 111(1), 62–65. Retrieved from http://w-ww.chemicke-listy.cz/ojs3/index.php/chemicke-listy/article/view/114

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